Dynamics and scaling of two-dimensional polymers in a dilute solution.
نویسندگان
چکیده
The breakdown of dynamical scaling for a dilute polymer solution in two dimensions has been suggested by Shannon and Choy [Phys. Rev. Lett. 79, 1455 (1997)]. However, we show here through extensive computer simulations that dynamical scaling holds when the relevant dynamical quantities are properly extracted from finite systems. To verify dynamical scaling, we present results based on mesoscopic simulations in two dimensions for a polymer chain in a good solvent with full hydrodynamic interactions. We also present analytical arguments for the size dependence of the diffusion coefficient and find excellent agreement with the present large-scale simulations.
منابع مشابه
Dynamics and scaling of polymers in a dilute solution: analytical treatment in two and higher dimensions.
We consider the dynamical scaling of a single polymer chain in good solvent. In the case of two-dimensional systems, Shannon and Choy [Phys. Rev. Lett. 79, 1455 (1997)] have suggested that the dynamical scaling for a dilute polymer solution breaks down. Using scaling arguments and analytical calculations based on the Zimm model, we show that the dynamical scaling of a dilute two-dimensional pol...
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عنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 68 5 Pt 1 شماره
صفحات -
تاریخ انتشار 2003